Azolium cyclophanes

被引:22
作者
Baker, Murray V. [1 ]
Brown, David H. [1 ]
机构
[1] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Nedlands, WA 6009, Australia
关键词
cyclophanes; azolium cyclophanes; supramolecular chemistry; imidazolium; anion binding; NHC carbenes;
D O I
10.2174/157019306778742869
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review covers the synthesis, conformational analysis, mass spectrometry, and reactivity and supramolecular chemistry of azolium cyclophanes. Included is a comprehensive coverage of the structural diversity of azolium cyclophanes. Aspects of reactivity examined include anion binding, carbene formation and metal coordination chemistry and H/D exchange.
引用
收藏
页码:333 / 354
页数:22
相关论文
共 73 条
[11]  
ALCALDE E, 1995, SYNLETT, P757
[12]  
Alcalde E, 1996, SYNLETT, P285
[13]  
Alcalde E, 2000, RAPID COMMUN MASS SP, V14, P1014, DOI 10.1002/(SICI)1097-0231(20000615)14:11<1014::AID-RCM982>3.0.CO
[14]  
2-N
[15]   A STABLE CRYSTALLINE CARBENE [J].
ARDUENGO, AJ ;
HARLOW, RL ;
KLINE, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) :361-363
[16]   ELECTRONIC STABILIZATION OF NUCLEOPHILIC CARBENES [J].
ARDUENGO, AJ ;
DIAS, HVR ;
HARLOW, RL ;
KLINE, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5530-5534
[17]   Synthesis and structure of N-heterocyclic carbene complexes of rhodium and iridium derived from an imidazolium-linked cyclophane [J].
Baker, MV ;
Brayshaw, SK ;
Skelton, BW ;
White, AH ;
Williams, CC .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (09) :2312-2322
[18]   Azolium-linked cyclophanes:: A comprehensive examination of conformations by 1H NMR spectroscopy and structural studies [J].
Baker, MV ;
Bosnich, MJ ;
Brown, DH ;
Byrne, LT ;
Hesler, VJ ;
Skelton, BW ;
White, AH ;
Williams, CC .
JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (22) :7640-7652
[19]   Dinuclear N-heterocyclic carbene complexes of silver(I), derived from imidazolium-linked cyclophanes [J].
Baker, MV ;
Brown, DH ;
Haque, RA ;
Skelton, BW ;
White, AH .
DALTON TRANSACTIONS, 2004, (21) :3756-3764
[20]   Synthesis and characterization of a saddle-shaped nickel-carbene complex derived from an imidazolium-linked meta-cyclophane [J].
Baker, MV ;
Skelton, BW ;
White, AH ;
Williams, CC .
ORGANOMETALLICS, 2002, 21 (13) :2674-2678