Oligothiophene-based catenanes:: Synthesis and electronic properties of a novel conjugated topological structure

被引：69

作者：

Baeuerle, Peter

Ammann, Martin

Wilde, Markus

Goetz, Guenther

Mena-Osteritz, Elena

Rang, Alexander

Schalley, Christoph A.

机构：

[1] Univ Ulm, Inst Organ Chem & Neue Mat 2, D-89081 Ulm, Germany

[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 03期

关键词：

catenanes; conjugation; noncovalent interactions; oligothiophenes; template synthesis;

D O I：

10.1002/anie.200602652

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Make it a double: A double metal template strategy has been used to form a π-conjugated catenane" consisting of inter-twined macrocycles with oligothienyl and phenanthroline units (see calculated structure). The optical and redox properties as well as the structural and conformational analyses give clear evidence that the two macrocycles in the catenane influence each other by through-space donor-acceptor interactions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA."

引用

页码：363 / 368

页数：6

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[1] Interlocked and intertwined structures and superstructures [J].