Air-Stable Diaminophosphine Sulfides as Preligands for Nickel-Catalyzed Cross-Couplings of Unactivated Fluoro(hetero)arenes

被引：38

作者：

Ackermann, Lutz ^{[1
]}

Wechsler, Cindy ^{[1
]}

Kapdi, Anant R. ^{[1
]}

Althammer, Andreas ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

SYNLETT | 2010年 / 02期

关键词：

fluoroarenes; Grignard reagents; ligands; nickel; secondary phosphine sulfide; C-F ACTIVATION; GRIGNARD-REAGENTS; PHOSPHINE OXIDES; BOND ACTIVATION; ARYL FLUORIDES; ARYLATIONS; HYDRODEFLUORINATION; COMPLEXES; CHLORIDES; HALIDES;

D O I：

10.1055/s-0029-1219166

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Air-stable secondary diaminophosphine sulfide preligands enable challenging nickel-catalyzed cross-coupling reactions of electron-deficient as well as electron-rich fluoro(hetero)arenes as electrophiles.

引用

页码：294 / 298

页数：5

共 49 条

[1] Catalytic arylation reactions by C-H bond activation with aryl tosylates
Ackermann, L
Althammer, A
Born, R
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[2] Air-stable phosphine oxides as preligands for catalytic activation reactions of C-Cl, C-F, and C-H bonds
Ackermann, L
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[J]. PURE AND APPLIED CHEMISTRY, 2006, 78 (02) : 209 - 214
[3] Cross-coupling reactions of aryl and vinyl chlorides catalyzed by a palladium complex derived from an air-stable H-phosphonate
Ackermann, L
Gschrei, CJ
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[J]. CHEMICAL COMMUNICATIONS, 2006, (13) : 1419 - 1421
[4] Efficient aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds using nickel complexes of air-stable phosphine oxides
Ackermann, L
Born, R
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (44) : 7216 - 7219
[5] Phosphine oxides as preligands in ruthenium-catalyzed arylations via C-H bond functionalization using aryl chlorides
Ackermann, L
[J]. ORGANIC LETTERS, 2005, 7 (14) : 3123 - 3125
[6] Dehydrative Direct Arylations of Arenes with Phenols via Ruthenium-Catalyzed C-H and C-OH Bond Functionalizations
Ackermann, Lutz
Mulzer, Michael
[J]. ORGANIC LETTERS, 2008, 10 (21) : 5043 - 5045
[7] Catalytic arylations with challenging substrates: From air-stable HASPO preligands to indole syntheses and C-H-bond functionalizations
Ackermann, Lutz
[J]. SYNLETT, 2007, (04) : 507 - 526
[8] A diaminochlorophosphine for palladium-catalyzed arylations of amines and ketones
Ackermann, Lutz
Spatz, Julia H.
Gschrei, Christian J.
Born, Robert
Althammer, Andreas
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (45) : 7627 - 7630
[9] Air-stable PinP(O)H as preligand for palladium-catalyzed Kumada couplings of unactivated tosylates
Ackermann, Lutz
Althammer, Andreas
[J]. ORGANIC LETTERS, 2006, 8 (16) : 3457 - 3460
[10] Air- and moisture-stable secondary phosphine oxides as preligands in catalysis
Ackermann, Lutz
[J]. SYNTHESIS-STUTTGART, 2006, 10 (10): : 1557 - 1571

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