Cobalt-Catalyzed Arylation or Benzylation of 2-Chloro-4,6-dimethoxy-1,3,5-triazine

被引：16

作者：

Begouin, Jeanne Marie ^{[2
]}

Claudel, Stephanie ^{[2
]}

Gosmini, Corinne ^{[1
,2
]}

机构：

[1] Ecole Polytech, CNRS, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

[2] Univ Paris 12, CNRS, ICMPE, UMR7182, F-94320 Thiais, France

来源：

SYNLETT | 2009年 / 19期

关键词：

cobalt; catalysis; cross-coupling; arylation; azo compounds; CROSS-COUPLING REACTIONS; AROMATIC KETONES; ARYL BROMIDES; CHLORIDES; REAGENTS; DERIVATIVES; HALIDES; INHIBITORS; AGENTS;

D O I：

10.1055/s-0029-1218307

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of functionalized aryl bromides or benzyl chlorides were coupled with 2-chloro-4.6-dimethoxy-1,3,5-trazine in good yields by a one-step procedure via cobalt catalysis.

引用

页码：3192 / 3194

页数：3

共 28 条

[1] Synthesis of functionalised diarylmethanes via a cobalt-catalysed cross-coupling of arylzinc species with benzyl chlorides [J].

Amatore, Muriel ;

Gosmini, Corinne .

CHEMICAL COMMUNICATIONS, 2008, (40) :5019-5021

[2] Cobalt-Catalyzed Cross-Coupling Between In Situ Prepared Arylzinc Halides and 2-Chloropyrimidine or 2-Chloropyrazine [J].

Begouin, Jeanne-Marie ;

Gosmini, Corinne .

JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (08) :3221-3224

[3] Iron-catalyzed reactions in organic synthesis [J].

Bolm, C ;

Legros, J ;

Le Paih, J ;

Zani, L .

CHEMICAL REVIEWS, 2004, 104 (12) :6217-6254

[4] Highly chemo- and stereoselective Fe-catalyzed alkenylation of organomanganese reagents [J].

Cahiez, G ;

Marquais, S .

TETRAHEDRON LETTERS, 1996, 37 (11) :1773-1776

[5] Iron-Catalyzed Oxidative Heterocoupling Between Aliphatic and Aromatic Organozinc Reagents: A Novel Pathway for Functionalized Aryl-Alkyl Cross-Coupling Reactions [J].

Cahiez, Gerard ;

Foulgoc, Laura ;

Moyeux, Alban .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (16) :2969-2972

[6] A New Efficient Catalytic System for the Chemoselective Cobalt-Catalyzed Cross-Coupling of Aryl Grignard Reagents with Primary and Secondary Alkyl Bromides [J].

Cahiez, Gerard ;

Chaboche, Christophe ;

Duplais, Christophe ;

Moyeux, Alban .

ORGANIC LETTERS, 2009, 11 (02) :277-280

[7] NOVEL PYRIMIDINE AND 1,3,5-TRIAZINE HYPOLIPIDEMIC AGENTS [J].

DATRI, G ;

GOMARASCA, P ;

RESNATI, G ;

TRONCONI, G ;

SCOLASTICO, C ;

SIRTORI, CR .

JOURNAL OF MEDICINAL CHEMISTRY, 1984, 27 (12) :1621-1629

[8] NEW TRIAZINE DERIVATIVES AS POTENT MODULATORS OF MULTIDRUG RESISTANCE [J].

DHAINAUT, A ;

REGNIER, G ;

ATASSI, G ;

PIERRE, A ;

LEONCE, S ;

KRAUSBERTHIER, L ;

PROST, JF .

JOURNAL OF MEDICINAL CHEMISTRY, 1992, 35 (13) :2481-2496

[9]

Diederich F., 1998, Metal-Catalyzed Cross-Coupling Reactions

[10] Convenient method for the preparation of aromatic ketones from acyl chlorides and arylzinc bromides using a cobalt catalysis [J].

Fillon, H ;

Gosmini, C ;

Périchon, J .

TETRAHEDRON, 2003, 59 (41) :8199-8202

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