Structurally characterized intermediates in the stepwise insertion of CO-ethylene or CO-methyl acrylate into the metal-carbon bond of Pd(II) complexes stabilized by (phosphinomethyl)oxazoline ligands

被引:37
作者
Agostinho, Magno [1 ]
Braunstein, Pierre [1 ]
机构
[1] Univ Strasbourg, Chim Coordinat Lab, CNRS,UMR 7177, Inst Chim, F-67070 Strasbourg, France
关键词
D O I
10.1039/b613865a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The initial CO-ethylene or CO-methyl acrylate insertion steps into the Pd-Me bond of methylpalladium(II) complexes with (phosphinomethyl)oxazoline ligands, leading to metallacycles, have been fully characterized, including by X-ray diffraction.
引用
收藏
页码:58 / 60
页数:3
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