Constructing cerium supramolecular wheels and encapsulating uranium with a Schiff-base calixpyrrole ligand

被引：34

作者：

Arnold, Polly L. ^{[1
]}

Potter , Natalie A. ^{[1
]}

Carmichael, Christopher D. ^{[1
]}

Slawin, Alexandra M. Z. ^{[2
]}

Roussel, Paul ^{[3
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[3] Atom Weap Estab, Reading RG7 4PR, Berks, England

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 11期

基金：

英国工程与自然科学研究理事会;

关键词：

CRYSTAL-STRUCTURE; COMPLEXES; METAL; BI;

D O I：

10.1039/b921132b

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Trinuclear, supramolecular wheel structures are formed spontaneously from the metallation of a Schiff-base-pyrrole macrocycle by Ce3+ cations, while the related actinide U3+ cation is instead oxidised to U4+ and encapsulated by the macrocyclic framework.

引用

页码：1833 / 1835

页数：3

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