Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity

被引：1425

作者：

Giri, Ramesh ^{[2
]}

Shi, Bing-Feng ^{[1
]}

Engle, Keary M. ^{[1
]}

Maugel, Nathan ^{[3
]}

Yu, Jin-Quan ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

[2] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

[3] Brandeis Univ, Dept Chem, Waltham, MA 02453 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 11期

基金：

美国国家科学基金会;

关键词：

ASYMMETRIC ALLYLIC OXIDATION; CARBON-HYDROGEN INSERTION; MARINE NATURAL-PRODUCTS; CATIONIC IR(I) COMPLEX; BOND ACTIVATION; INTRAMOLECULAR ALKYLATION; COUPLING POLYMERIZATION; CHIRAL RUTHENIUM; OXOVANADIUM(IV) COMPLEXES; STEREOSELECTIVE-SYNTHESIS;

D O I：

10.1039/b816707a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This critical review discusses historical and contemporary research in the field of transition metal-catalyzed carbon-hydrogen (C-H) bond activation through the lens of stereoselectivity. Research concerning both diastereoselectivity and enantioselectivity in C-H activation processes is examined, and the application of concepts in this area for the development of novel carbon-carbon and carbon-heteroatom bond-forming reactions is described. Throughout this review, an emphasis is placed on reactions that are (or may soon become) relevant in the realm of organic synthesis (221 references).

引用

页码：3242 / 3272

页数：31

共 228 条

[51] ASYMMETRIC-SYNTHESIS OF LACTONES WITH HIGH ENANTIOSELECTIVITY BY INTRAMOLECULAR CARBON HYDROGEN INSERTION REACTIONS OF ALKYL DIAZOACETATES CATALYZED BY CHIRAL RHODIUM(II) CARBOXAMIDES [J].