Six-coordinated Cd(II) centers as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

被引：23

作者：

Cordes, David B.

Hanton, Lyall R.

Spicer, Mark D.

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

[2] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 02期

关键词：

D O I：

10.1021/cg0604632

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH(+) led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an alpha-polonium network.

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页码：328 / 336

页数：9

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