Six-coordinated Cd(II) centers as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

被引:23
作者
Cordes, David B.
Hanton, Lyall R.
Spicer, Mark D.
机构
[1] Univ Otago, Dept Chem, Dunedin, New Zealand
[2] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
关键词
D O I
10.1021/cg0604632
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH(+) led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an alpha-polonium network.
引用
收藏
页码:328 / 336
页数:9
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