Elastic and frictional properties of graphene

被引:349
作者
Lee, Changgu [1 ]
Wei, Xiaoding [1 ]
Li, Qunyang [2 ]
Carpick, Robert [2 ]
Kysar, Jeffrey W. [1 ]
Hone, James [1 ]
机构
[1] Columbia Univ, New York, NY 10025 USA
[2] Univ Penn, Philadelphia, PA 19104 USA
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2009年 / 246卷 / 11-12期
基金
美国国家科学基金会;
关键词
MULTIWALLED CARBON NANOTUBES; STRENGTH;
D O I
10.1002/pssb.200982329
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We describe studies of the elastic properties and frictional characteristics of graphene samples of varying thickness using an atomic force microscope. For tensile testing, graphene is suspended over micron-sized circular holes and indented by atomic force microscope (AFM) tips. Fitting of the force-displacement curves yields the prestress and elastic stiffness, while comparison of the breaking force to simulation gives the ultimate strength, which is the highest measured for any material. Experiments on samples with 1-3 atomic layers yield similar values for the intrinsic stiffness and strength of a single sheet, but also reveal differences in mechanical behavior with thickness. The frictional force between an AFM tip and graphene decreases with thickness for samples from 1 to 4 layers, and does not depend on the presence of a substrate. High-resolution friction force imaging in stick-slip mode shows the same trend, and allows direct imaging of the crystal lattice. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA. Weinheim
引用
收藏
页码:2562 / 2567
页数:6
相关论文
共 26 条
[1]   LATTICE-DYNAMICAL MODEL FOR GRAPHITE [J].
ALJISHI, R ;
DRESSELHAUS, G .
PHYSICAL REVIEW B, 1982, 26 (08) :4514-4522
[2]  
Bhatia NM, 1968, Int J Non Lin Mech, V3, P307, DOI [DOI 10.1016/0020-7462(68)90004-8, 10.1016/0020-7462(68)90004-8]
[3]   ELASTIC CONSTANTS OF COMPRESSION-ANNEALED PYROLYTIC GRAPHITE [J].
BLAKSLEE, OL .
JOURNAL OF APPLIED PHYSICS, 1970, 41 (08) :3373-+
[4]   Intrinsic ripples in graphene [J].
Fasolino, A. ;
Los, J. H. ;
Katsnelson, M. I. .
NATURE MATERIALS, 2007, 6 (11) :858-861
[5]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[6]   Friction and Dissipation in Epitaxial Graphene Films [J].
Filleter, T. ;
McChesney, J. L. ;
Bostwick, A. ;
Rotenberg, E. ;
Emtsev, K. V. ;
Seyller, Th. ;
Horn, K. ;
Bennewitz, R. .
PHYSICAL REVIEW LETTERS, 2009, 102 (08)
[7]   Atomic structure of graphene on SiO2 [J].
Ishigami, Masa ;
Chen, J. H. ;
Cullen, W. G. ;
Fuhrer, M. S. ;
Williams, E. D. .
NANO LETTERS, 2007, 7 (06) :1643-1648
[8]   The mechanical response of freestanding circular elastic films under point and pressure loads [J].
Komaragiri, U ;
Begley, MR .
JOURNAL OF APPLIED MECHANICS-TRANSACTIONS OF THE ASME, 2005, 72 (02) :203-212
[9]  
Lawn B., 1993, FRACTURE BRITTLE SOL, P194
[10]   Measurement of the elastic properties and intrinsic strength of monolayer graphene [J].
Lee, Changgu ;
Wei, Xiaoding ;
Kysar, Jeffrey W. ;
Hone, James .
SCIENCE, 2008, 321 (5887) :385-388