Synthesis, X-ray structures, spectroscopic and electrochemical properties of ruthenium(II) complexes containing 2,2′-bipyrimidine

被引：68

作者：

Ji, Z ^{[1
]}

Huang, SD ^{[1
]}

Guadalupe, AR ^{[1
]}

机构：

[1] Univ Puerto Rico, Dept Chem, Rio Piedras, PR 00931 USA

来源：

INORGANICA CHIMICA ACTA | 2000年 / 305卷 / 02期

关键词：

crystal structures; electrochemistry; ruthenium complexes; polypyridyl complexes;

D O I：

10.1016/S0020-1693(00)00123-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ruthenium polypyridyl complexes containing 2,2'-bipyrimidine, [Ru(bpy)(2)bpm](PF6)(2) (I) and [Ru(phen)(2)bpm](PF6)(2) (II), were synthesized with high yield and purity. An extensive characterization was carried out using ESMS, UV-Vis, H-1 and C-13 NMR, electrochemistry and X-ray single crystal diffraction analysis. The experimental results show that the spectroscopic and electrochemical properties of I and II are similar to those of their parent complexes [Ru(bpy)(3)](PF6)(2) and [Ru(phen)(3)](PF6)(2). This indicates that both I and II can be used as building blocks for the construction of molecular devices. (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：127 / 134

页数：8

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