Total synthesis of both enantiomers of 15-oxopuupehenol methylenedioxy derivatives

被引：36

作者：

Arjona, O ^{[1
]}

Garranzo, M ^{[1
]}

Mahugo, J ^{[1
]}

Maroto, E ^{[1
]}

Plumet, J ^{[1
]}

Saez, B ^{[1
]}

机构：

[1] UNIV COMPLUTENSE,FAC QUIM,DEPT QUIM ORGAN 1,E-28040 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(97)01683-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of both enantiomers of puupehenol and 15-oxopuupehenol as methylenedioxy derivatives is described. The key steps of the synthesis are the regioselective transformation of 10 to 11 and the stereoselective cyclization of 12 to 13. (C) 1997 Elsevier Science Ltd.

引用

页码：7249 / 7252

页数：4

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