Benzylation of carboxylic acids by oxidation-reduction condensation using quinones and benzyloxydiphenylphosphine

被引:11
作者
Mukaiyama, T [1 ]
Shintou, T [1 ]
Kikuchi, W [1 ]
机构
[1] TCI, Ctr Basic Res, Kitasato Inst, Kita Ku, Tokyo 1140003, Japan
关键词
D O I
10.1246/cl.2002.1126
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Various carboxylic benzyl esters were obtained in high yields by way of oxidation-reduction condensation in which benzyloxy-diphenylphosphine (BDPP), having been prepared easily from chlorodiphenylphosphine and benzyl alcohol, was treated with various carboxylic acids in the presence of 2,6-dimethyl-1,4-benzoquinone(DMBQ) under mild conditions.
引用
收藏
页码:1126 / 1127
页数:2
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[11]   NOVEL REACTIVITY OF STABILIZED METHYLENETRIBUTYLPHOSPHORANE - A NEW MITSUNOBU REAGENT [J].
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