Gas-Phase Synthesis and Intense Visible Absorption of Tryptophan-Gold Cations

被引：19

作者：

Antoine, Rodolphe ^{[1
]}

Bertorelle, Franck ^{[1
]}

Broyer, Michel ^{[1
]}

Compagnon, Isabelle ^{[1
]}

Dugourd, Philippe ^{[1
]}

Kulesza, Alexander ^{[2
]}

Mitric, Roland ^{[3
]}

Bonacic-Koutecky, Vlasta ^{[2
]}

机构：

[1] Univ Lyon 1, CNRS, UMR5579, LASIM, F-69622 Villeurbanne, France

[2] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

[3] Free Univ Berlin, Fachbereich Phys, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 42期

关键词：

ab initio calculations; absorption; charge transfer; gold; mass spectrometry; RESONANCE ENERGY-TRANSFER; CELL-TARGETING AGENTS; IN-SITU SYNTHESIS; IDENTITY APPROXIMATION; NANOPARTICLES; DENSITY; PROTEIN; SILVER; SPECTROSCOPY; RESOLUTION;

D O I：

10.1002/anie.200902882

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The color of gold: The tryptophan-gold cation was synthesized and its unique optical properties were studied experimentally and by ab initio calculations (see picture). The complex exhibits strong absorption in the visible region owing to charge-transfer excitations, which make gold complexes attractive for bioapplications. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA,.

引用

收藏

页码：7829 / 7832

页数：4

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