Synthesis and characterization of water-soluble amino fullerene derivatives

被引：100

作者：

Richardson, CF ^{[1
]}

Schuster, DI ^{[1
]}

Wilson, SR ^{[1
]}

机构：

[1] NYU, Dept Chem, New York, NY 10003 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 08期

关键词：

D O I：

10.1021/ol990312a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of amino-substituted methanofullerene derivatives were prepared by mono, tris-, and hexa Bingel-Hirsch reactions using an N-protected malonate derivative, Upon scission of the protecting groups, the e,e,e-tris- and octahedral T-h hexa-methano amino fullerenes were found to be among the most water-soluble fullerene derivatives yet prepared. He-3 NMR data on corresponding adducts of He-3@C-60 helped verify the assigned structures. UV spectral studies confirmed the influence of aggregation on solubility of these adducts in water.

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页码：1011 / 1014

页数：4

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