Coupled-oscillator model for nonlinear optical activity

被引：35

作者：

Belkin, MA

Shen, YR ^{[1
]}

Flytzanis, C

机构：

[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA

[3] Ecole Normale Super, Phys Mat Condensee Lab, F-75231 Paris 05, France

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 363卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(02)01189-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The coupled-oscillator model, previously used to describe linear optical activity, is extended to the study of nonlinear optical activity of dimer-like chiral molecules. The result shows good agreement between theory and experiment for optically active sum-frequency generation from 1,1'-bi-2-naphthol solution. It is seen that linear and nonlinear optical activities generally probe different aspects of the chiral structure of the molecules. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：479 / 485

页数：7

共 17 条

[1]

BARRON LD, 1982, MOL LIGHT SCATTERING, pCH5

[2] Sum-frequency vibrational spectroscopy on chiral liquids: A novel technique to probe molecular chirality [J].