Propylene carbonate stabilized nanostructured palladium clusters as catalysts in Heck reactions

被引：289

作者：

Reetz, MT

Lohmer, G

机构：

[1] Max-Planck-Inst. F. Kohlenforschung, D-45470 Mülheim/Ruhr

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 16期

关键词：

D O I：

10.1039/cc9960001921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanostructured Pd clusters, prepared either electrochemically using a sacrificial Pd anode or by thermolysis of Pd(O(2)CMe)(2), are stable in propylene carbonate even at 140-155 degrees C; such colloidal solutions catalyse Heck reactions in the absence of phosphine ligands.

引用

页码：1921 / 1922

页数：2

共 33 条

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