New chiral ligands and iron(III) complexes based on 2,6-bis(1-benzyl-4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-on-2-yl)pyridines

被引：29

作者：

Sedlák, M

Drabina, P

Cisarová, I

Ruzicka, A

Hanusek, J

Machácek, V

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Organ Chem, Pardubice 53210, Czech Republic

[2] Charles Univ, Fac Sci, Dept Inorgan Chem, Prague 12843 2, Czech Republic

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 41期

关键词：

D O I：

10.1016/j.tetlet.2004.08.085

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New ligands and their complexes with iron(III) chloride have been suggested and prepared: (R,S)-, (R,R)- and (S,S)-2,6-bis(1-benzyl-4-isopropyl-4-methyl-4,5-dihydro-1H-imidazol-5-on-2-yl) pyridines. Both the ligands and their complexes were characterised by H-1 and C-13 NMR spectroscopy, optical rotation and X-ray diffraction. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：7723 / 7726

页数：4

共 21 条

[1] MANGANESE(II) AND IRON(III) COMPLEXES OF THE TRIDENTATE LIGANDS BIS(BENZ-IMIDAZOL-2-YLMETHYL)-AMINE (L1) AND BIS(BENZ-IMIDAZOL-2-YLMETHYL)-METHYLAMINE (L2) - CRYSTAL-STRUCTURES OF [MNL1(CH3CO2)2], [FEL2CL3], AND [FE2L12(MU-O)(MU-(CH3)3CCO2)2][CLO4]2 [J].