Generation and reactions of organic radical cations in zeolites

被引：275

作者：

García, H

Roth, HD

机构：

[1] Univ Politecn Valencia, Dept Quim, Inst Tecnol Quim, UPV CSIC, E-46071 Valencia, Spain

[2] Rutgers State Univ, Dept Chem & Chem Biol, Wright Rieman Labs, Piscataway, NJ 08854 USA

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 11期

关键词：

D O I：

10.1021/cr980026x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review illustrates that zeolites are a large family of versatile, well-characterized acid catalysts, whose structure and properties are relatively well understood. Focus is on their ability to generate spontaneously organic radical cations or to serve as hosts in which these species can be stabilized after chemical, photochemical, or electrochemical generation.

引用

页码：3947 / 4007

页数：61

共 559 条

[1] AALSBERSBERG WJ, 1959, J CHEM SOC, P3049
[2] Photochemical and chemical electron transfer reactions of bicyclo[2.1.0]pentanes (housanes) in solution and in zeolite cavities
Adam, W
Corma, A
Miranda, MA
SabaterPicot, MJ
Sahin, C
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (10) : 2380 - 2386
[3] The selective catalytic oxidation of silanes to silanols with H2O2 activated by the Ti-beta zeolite
Adam, W
Garcia, H
Mitchell, CM
Saha-Möller, CR
Weichold, O
[J]. CHEMICAL COMMUNICATIONS, 1998, (23) : 2609 - 2610
[4] Charge transfer complexes between methylviologen and aromatic donors within faujasite Y: Influence of the alkaline metal counter cations
Alvaro, M
Garcia, H
Garcia, S
Fernandez, L
[J]. TETRAHEDRON LETTERS, 1996, 37 (16) : 2873 - 2876
[5] Intrazeolite photochemistry .17. Zeolites as electron donors: Photolysis of methylviologen incorporated within zeolites
Alvaro, M
Garcia, H
Garcia, S
Marquez, F
Scaiano, JC
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (16): : 3043 - 3051
[6] Remarkably high electrochemical charge uptake for modified electrodes of polyacetylene molecular wires encapsulated within zeolites and mesoporous MCM-41 aluminosilicate
Alvaro, M
Ferrer, B
García, H
Lay, A
Trinidad, F
Valenciano, J
[J]. CHEMICAL PHYSICS LETTERS, 2002, 356 (5-6) : 577 - 584
[7] EXPERIMENTS AND CALCULATIONS FOR DETERMINATION OF THE STABILITIES OF BENZYL, BENZHYDRYL, AND FLUORENYL CARBOCATIONS - ANTIAROMATICITY REVISITED
AMYES, TL
RICHARD, JP
NOVAK, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) : 8032 - 8041
[8] ANISIMOV OA, 1979, PHYS CHEM, V248, P380
[9] Photocatalytic reduction of CO2 with H2O on titanium oxides anchored within micropores of zeolites: Effects of the structure of the active sites and the addition of Pt
Anpo, M
Yamashita, H
Ichihashi, Y
Fujii, Y
Honda, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14): : 2632 - 2636
[10] ARGAUER RJ, 1982, Patent No. 3702886

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