Nanometer-Sized Fluorous Fullerene Vesicles in Water and on Solid Surfaces

被引：53

作者：

Homma, Tatsuya ^{[1
]}

Harano, Koji ^{[1
]}

Isobe, Hiroyuki ^{[1
]}

Nakamura, Eiichi ^{[1
,2
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Japan Sci & Technol Agcy, Nakamura Funct Carbon Cluster Project, Exploratory Res Adv Technol ERATO, Tokyo 1130033, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 09期

关键词：

fluorine; fullerenes; self-assembly; wettability; vesicles; DELIVERY;

D O I：

10.1002/anie.200904659

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"Chemical Equation Presented" A new twist for bucky balls: A fluorous fullerene amphiphile lacking the conventional polar head /nonpolar tail motif forms a vesicle in water (see picture, F green, C gray), mediated by the cohesive power of fullerene. The fluorous moiety covers the vesicle surface, and vesicle solutions dissolve perfluorooctane. Unlike lipid vesicles, the fluorous vesicle is very robust and retains its spherical shape even on a solid substrate under high vacuum. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1665 / 1668

页数：4

共 31 条

[11] Gene delivery by aminofullerenes: Structural requirements for efficient transfection [J].

Isobe, Hiroyuki ;

Nakanishi, Waka ;

Tomita, Naoki ;

Jinno, Shigeki ;

Okayama, Hiroto ;

Nakamura, Eiichi .

CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (1-2) :167-175

[12] SOLUBILITY OF FLUOROCARBONS IN WATER AS A KEY PARAMETER DETERMINING FLUOROCARBON EMULSION STABILITY [J].

KABALNOV, AS ;

MAKAROV, KN ;

SHCHERBAKOVA, OV .

JOURNAL OF FLUORINE CHEMISTRY, 1990, 50 (03) :271-284

[13] Layered paving of vesicular nanoparticles formed with cerasome as a bioinspired organic-inorganic hybrid [J].

Katagiri, K ;

Hamasaki, R ;

Ariga, K ;

Kikuchi, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :7892-7893

[14] Fluorous-based carbohydrate microarrays [J].

Ko, KS ;

Jaipuri, FA ;

Pohl, NL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (38) :13162-13163

[15] A water-soluble fullerene vesicle alleviates angiotensin II-induced oxidative stress in human umbilical venous endothelial cells [J].

Maeda, Rui ;

Noiri, Eisei ;

Isobe, Hiroyuki ;

Homma, Tatsuya ;

Tanaka, Tamami ;

Negishi, Kousuke ;

Doi, Kent ;

Fujita, Toshiro ;

Nakamura, Eiichi .

HYPERTENSION RESEARCH, 2008, 31 (01) :141-151

[16] X-ray crystallographic characterization of potassium pentaphenyl[60]fullerene [J].

Matsuo, Y ;

Tahara, K ;

Nakamura, E .

CHEMISTRY LETTERS, 2005, 34 (08) :1078-1079

[17] Selective multiaddition of organocopper reagents to fullerenes [J].

Matsuo, Yutaka ;

Nakamura, Eiichi .

CHEMICAL REVIEWS, 2008, 108 (08) :3016-3028

[18]

Quiñonero D, 2002, ANGEW CHEM INT EDIT, V41, P3389, DOI 10.1002/1521-3773(20020916)41:18<3389::AID-ANIE3389>3.0.CO

[19]

2-S

[20]

Quinonero D., 2002, Angew. Chem. Int. Ed, V114, P3539, DOI [10.1002/1521-3757(20020916)114:18andlt

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