The mechanism of lithiation and nitrile insertion reactions of β-methylazines:: evidence from the structure of 3-C5H4NCH=C(Ph)N(H)C(Ph)=NLi.PMDETA

被引：20

作者：

Ball, SC ^{[1
]}

Davies, RP ^{[1
]}

Raithby, PR ^{[1
]}

Shields, GP ^{[1
]}

Snaith, R ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 550卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

lithium; reaction mechanisms; nitriles; X-ray structure;

D O I：

10.1016/S0022-328X(97)00553-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 1:1:1 reaction of 3-methylpyridine, 1, with LDA and PhCN in the presence of PMDETA gives the title complex 6, shown by X-ray crystallography to be the first monomeric iminolithium. The isolation of 6, and of a cyclised product 8 when a 3:10:3 reaction of 1:LDA:PhCN is carried out, suggest a mechanism for previously published cyclisation reactions of beta-methylazines. (C) 1998 Elsevier Science S.A.

引用

收藏

页码：457 / 461

页数：5

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