Accurate level energies in the EF1Σg+, GK1Σg+, H1Σg+, B1Σu+, C1Πu, B′1Σu+, D1Πu, I1Πg, J1Δg states of H2

被引:65
作者
Bailly, D. [2 ]
Salumbides, E. J. [1 ]
Vervloet, M. [3 ]
Ubachs, W. [1 ]
机构
[1] Vrije Univ Amsterdam, Ctr Laser, NL-1081 HV Amsterdam, Netherlands
[2] Univ Paris 11, Photophys Mol Lab, F-91405 Orsay, France
[3] Synchrotron Soleil, F-91192 Gif Sur Yvette, France
关键词
molecular hydrogen; Fourier transform spectroscopy; extreme ultraviolet; proton-electron mass ratio; accurate level energies; AB-INITIO CALCULATION; RESOLUTION LASER SPECTROSCOPY; DOUBLE-RESONANCE EXCITATION; ANGULAR-MOMENTUM STATES; DOUBLE-MINIMUM STATE; ELECTRON MASS-RATIO; HYDROGEN MOLECULE; VIBRATIONAL LEVELS; IONIZATION-POTENTIALS; GROUND-STATE;
D O I
10.1080/00268970903413350
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By combining results from a Doppler-free two-photon laser excitation study on several lines in the EF1 Sigma(+)(g)-X-1 Sigma(+)(g) (0,0) band of H-2 with results from a Fourier-transform spectroscopic study on a low-pressure discharge in hydrogen, absolute level energies, with respect to the X-1 Sigma(+)(g), v = 0, N = 0 ground level, were determined for 547 rovibronically excited states in H2. While for some of the levels in the EF1 Sigma(+)(g) and B-1 Sigma(+)(u) states the uncertainties are as low as 0.0001 cm(-1), the accuracy of other levels is lower. The general improvement in the accuracy for the comprehensive data set of level energies is by an order of magnitude with respect to previous measurements. An updated listing of transition wavelengths of the spectral lines in the Lyman and Werner bands is presented, based on combination differences between the presently obtained B-1 Sigma(+)(u) and C-1 Pi(u) level energies and those in the X-1 Sigma(+)(g) ground state.
引用
收藏
页码:827 / 846
页数:20
相关论文
共 89 条
[11]   Spectroscopy on some g symmetry states in H2 and determination of the ionization potential -: art. no. 064501 [J].
de Lange, A ;
Reinhold, E ;
Ubachs, W .
PHYSICAL REVIEW A, 2002, 65 (06) :4
[12]   The Spa of the Hydrogen Molecule [J].
Dieke, G. H. .
ZEITSCHRIFT FUR PHYSIK, 1929, 55 (7-8) :447-450
[13]   THE I1IIG STATE OF HYDROGEN - ADIABATIC CORRECTIONS, ENERGY-LEVELS, L-UNCOUPLING, AND ELECTRONIC-TRANSITION MOMENTS [J].
DRESSLER, K ;
WOLNIEWICZ, L .
CANADIAN JOURNAL OF PHYSICS, 1984, 62 (12) :1706-1712
[14]   EF AND GK 1-SIGMA+G STATES OF HYDROGEN - CALCULATION OF NON-ADIABATIC COUPLING [J].
DRESSLER, K ;
GALLUSSER, R ;
QUADRELLI, P ;
WOLNIEWICZ, L .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1979, 75 (02) :205-219
[15]   Lamb shift measurement in the 1 S-1 ground state of helium [J].
Eikema, KSE ;
Ubachs, W ;
Vassen, W ;
Hogervorst, W .
PHYSICAL REVIEW A, 1997, 55 (03) :1866-1884
[16]   PRECISE 2-PHOTON SPECTROSCOPY OF E-] X-STAR INTERVALS IN H-2 [J].
EYLER, EE ;
GILLIGAN, J ;
MCCORMACK, E ;
NUSSENZWEIG, A ;
POLLACK, E .
PHYSICAL REVIEW A, 1987, 36 (07) :3486-3489
[17]   The production of light by cathode rays [J].
Fulcher, GS .
ASTROPHYSICAL JOURNAL, 1911, 34 (05) :388-396
[18]   OPTICAL-PHASE PERTURBATIONS IN NANOSECOND PULSED AMPLIFICATION AND 2ND-HARMONIC GENERATION [J].
GANGOPADHYAY, S ;
MELIKECHI, N ;
EYLER, EE .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1994, 11 (01) :231-241
[19]  
GAYLUSSAC JL, 1809, MEM SOC ARCUEIL, V2, P207
[20]   AB INITIO CALCULATION OF EPSILON 1SIGMAG AND ALPHA 3SIGMAG+ STATES OF HYDROGEN MOLECULE [J].
GERHAUSER, J ;
TAYLOR, HS .
JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (10) :3621-+