Accurate level energies in the EF1Σg+, GK1Σg+, H1Σg+, B1Σu+, C1Πu, B′1Σu+, D1Πu, I1Πg, J1Δg states of H2

被引:64
作者
Bailly, D. [2 ]
Salumbides, E. J. [1 ]
Vervloet, M. [3 ]
Ubachs, W. [1 ]
机构
[1] Vrije Univ Amsterdam, Ctr Laser, NL-1081 HV Amsterdam, Netherlands
[2] Univ Paris 11, Photophys Mol Lab, F-91405 Orsay, France
[3] Synchrotron Soleil, F-91192 Gif Sur Yvette, France
关键词
molecular hydrogen; Fourier transform spectroscopy; extreme ultraviolet; proton-electron mass ratio; accurate level energies; AB-INITIO CALCULATION; RESOLUTION LASER SPECTROSCOPY; DOUBLE-RESONANCE EXCITATION; ANGULAR-MOMENTUM STATES; DOUBLE-MINIMUM STATE; ELECTRON MASS-RATIO; HYDROGEN MOLECULE; VIBRATIONAL LEVELS; IONIZATION-POTENTIALS; GROUND-STATE;
D O I
10.1080/00268970903413350
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By combining results from a Doppler-free two-photon laser excitation study on several lines in the EF1 Sigma(+)(g)-X-1 Sigma(+)(g) (0,0) band of H-2 with results from a Fourier-transform spectroscopic study on a low-pressure discharge in hydrogen, absolute level energies, with respect to the X-1 Sigma(+)(g), v = 0, N = 0 ground level, were determined for 547 rovibronically excited states in H2. While for some of the levels in the EF1 Sigma(+)(g) and B-1 Sigma(+)(u) states the uncertainties are as low as 0.0001 cm(-1), the accuracy of other levels is lower. The general improvement in the accuracy for the comprehensive data set of level energies is by an order of magnitude with respect to previous measurements. An updated listing of transition wavelengths of the spectral lines in the Lyman and Werner bands is presented, based on combination differences between the presently obtained B-1 Sigma(+)(u) and C-1 Pi(u) level energies and those in the X-1 Sigma(+)(g) ground state.
引用
收藏
页码:827 / 846
页数:20
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