Attempted stereocontrol at C-2′ of strigol-type compounds by a Michael reaction/elimination approach

被引：14

作者：

Röhrig, S

Hennig, L

Findeisen, M

Welzel, P

Frischmuth, K

Marx, A

Petrowitsch, T

Koll, P

Müller, D

Mayer-Figge, H

Sheldrick, WS

机构：

[1] Univ Leipzig, Fak Chem & Mineral, D-04103 Leipzig, Germany

[2] Ruhr Univ Bochum, Fak Chem, D-44780 Bochum, Germany

来源：

TETRAHEDRON | 1998年 / 54卷 / 14期

关键词：

D O I：

10.1016/S0040-4020(98)00076-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By a Michael addition/nucleophilic substitution/elimination sequence the stereocontrol at C-2' in strigol-typed compounds is in principle possible. However, the method is unsuitable for practical application since it has been shown that a stereolabile intermediate is involved. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3413 / 3438

页数：26

共 27 条

[21]

Schmidt R. R., 1986, ANGEW CHEM, V98, P213

[22] NEW METHODS FOR THE SYNTHESIS OF GLYCOSIDES AND OLIGOSACCHARIDES - ARE THERE ALTERNATIVES TO THE KOENIGS-KNORR METHOD [J].