Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation

被引：168

作者：

Geier, Stephen J. ^{[1
]}

Chase, Preston A. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 27期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ORGANOCATALYTIC TRANSFER HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; 1,2,3,4-TETRAHYDRO DERIVATIVES; REGIOSELECTIVE REDUCTION; H-2; ACTIVATION; PART; QUINOLINES; MECHANISM; PAIRS; CARBENE;

D O I：

10.1039/c0cc00719f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-Heterocycles form weak adducts with B(C6F5)(3) that exist in equilibrium with the corresponding FLP; nonetheless, these heterocycles are reduced in the presence of a catalytic amount of the borane B(C6F5)(3) and H-2.

引用

页码：4884 / 4886

页数：3

共 59 条

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