Effects of modulus and surface chemistry of thiol-ene photopolymers in nanoimprinting

被引:89
作者
Hagberg, Erik C.
Malkoch, Michael
Ling, Yibo
Hawker, Craig J.
Carter, Kenneth R.
机构
[1] Univ Massachusetts, Conte Ctr Polymer Res, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[2] IBM Corp, Almaden Res Ctr, San Jose, CA 95120 USA
[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
关键词
D O I
10.1021/nl061217f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thiol-ene photopolymers were studied as patternable resins for nanocontact molding imprint lithography. Photopolymerizable thiol and ene monomer mixtures were used, and after molding, patterned thiol-ene polymer features the size and shape of the original molds were replicated. Adhesion and release were examined and controlled by manipulating the surface chemistry of the substrate and mold. A direct correlation between cured thiol-ene polymer modulus and pattern fidelity was observed.
引用
收藏
页码:233 / 237
页数:5
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