Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

被引：145

作者：

Canty, Allan J. ^{[1
]}

机构：

[1] Univ Tasmania, Sch Chem, Hobart, Tas, Australia

来源：

DALTON TRANSACTIONS | 2009年 / 47期

基金：

澳大利亚研究理事会;

关键词：

BIDENTATE NITROGEN LIGANDS; OXYGEN BOND FORMATION; PT-PT COMPLEXES; C-H ACTIVATION; 2-HYDROXYPYRIDINATO BRIDGING LIGANDS; FORMING REDUCTIVE ELIMINATION; ALKYL HALIDE TRANSFER; ORGANOMETALLIC CHEMISTRY; DINUCLEAR COMPLEXES; ADDITION-REACTIONS;

D O I：

10.1039/b914080h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This perspective focuses on the higher oxidation state (III, IV) organometallic chemistry of palladium involving a range of strong oxidants, with consideration of platinum chemistry where it is informative for the evaluation of structure and mechanism. Particular emphasis is placed on hypervalent iodine reagents, halogens and related oxidants of intense current interest in organic synthesis, together with linkages in concepts between this chemistry and recent advances in studies of diaryl disulfides, diaryl diselenides, and diaryl peroxides as oxidants.

引用

页码：10409 / 10417

页数：9

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