Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

被引：145

作者：

Canty, Allan J. ^{[1
]}

机构：

[1] Univ Tasmania, Sch Chem, Hobart, Tas, Australia

来源：

DALTON TRANSACTIONS | 2009年 / 47期

基金：

澳大利亚研究理事会;

关键词：

BIDENTATE NITROGEN LIGANDS; OXYGEN BOND FORMATION; PT-PT COMPLEXES; C-H ACTIVATION; 2-HYDROXYPYRIDINATO BRIDGING LIGANDS; FORMING REDUCTIVE ELIMINATION; ALKYL HALIDE TRANSFER; ORGANOMETALLIC CHEMISTRY; DINUCLEAR COMPLEXES; ADDITION-REACTIONS;

D O I：

10.1039/b914080h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This perspective focuses on the higher oxidation state (III, IV) organometallic chemistry of palladium involving a range of strong oxidants, with consideration of platinum chemistry where it is informative for the evaluation of structure and mechanism. Particular emphasis is placed on hypervalent iodine reagents, halogens and related oxidants of intense current interest in organic synthesis, together with linkages in concepts between this chemistry and recent advances in studies of diaryl disulfides, diaryl diselenides, and diaryl peroxides as oxidants.

引用

页码：10409 / 10417

页数：9

共 143 条

[11] TETRAMETHYLDIPLATINUM(III) (PT-PT) COMPLEXES WITH 2-HYDROXYPYRIDINATO BRIDGING LIGANDS
BANCROFT, DP
COTTON, FA
FALVELLO, LR
SCHWOTZER, W
[J]. INORGANIC CHEMISTRY, 1986, 25 (06) : 763 - 770
[12] TETRAMETHYLDIPLATINUM(III) (PT-PT) COMPLEXES WITH 2-HYDROXYPYRIDINATO BRIDGING LIGANDS .2. REVERSALS OF LIGAND ORIENTATIONS
BANCROFT, DP
COTTON, FA
[J]. INORGANIC CHEMISTRY, 1988, 27 (09) : 1633 - 1637
[13] TETRAMETHYLDIPLATINUM(III) (PT-PT) COMPLEXES WITH 2-HYDROXYPYRIDINATO BRIDGING LIGANDS .3. COMPOUNDS WITH DIETHYL SULFIDE AS THE AXIAL LIGAND
BANCROFT, DP
COTTON, FA
[J]. INORGANIC CHEMISTRY, 1988, 27 (22) : 4022 - 4025
[14] REACTIONS OF DERIVATIVES OF IODINE(III) WITH FERROPORPHYRINS AND CYTOCHROME-P-450 - FORMATION OF IRON(III) SIGMA-ARYL COMPLEXES AND IRON(II) N-ARYL-PORPHYRINS FROM DIARYLIODONIUM SALTS
BATTIONI, JP
DUPRE, D
DELAFORGE, M
JAOUEN, M
MANSUY, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 358 (1-3) : 389 - 400
[15] Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy=2,2′-bipyridine)
Bayler, A
Canty, AJ
Ryan, JH
Skelton, BW
White, AH
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (11) : 575 - 578
[16] Trimethyl-palladium(IV) and -platinum(IV) complexes containing phosphine donor ligands, including studies of 1,5,9-triethyl-1,5,9-triphosphacyclodecane and X-ray structural studies of palladium(II) and palladium(IV) complexes
Bayler, A
Canty, AJ
Edwards, PG
Skelton, BW
White, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (19): : 3325 - 3330
[17] OCTADIENYL-BRIDGED BIMETALLIC COMPLEXES OF PALLADIUM AS INTERMEDIATES IN TELOMERIZATION REACTIONS OF BUTADIENE
BEHR, A
VONILSEMANN, G
KEIM, W
KRUGER, C
TSAY, YH
[J]. ORGANOMETALLICS, 1986, 5 (03) : 514 - 518
[18] Synthesis, characterization, and electrochemical relationships of dinuclear complexes of platinum(II) and platinum(III) containing ortho-metalated tertiary arsine ligands
Bennett, MA
Bhargava, SK
Bond, AM
Edwards, AJ
Guo, SX
Privér, SH
Rae, AD
Willis, AC
[J]. INORGANIC CHEMISTRY, 2004, 43 (24) : 7752 - 7763
[19] OXYGEN INSERTION INTO PALLADIUM-ARENE BONDS BY IODOSYLBENZENE
BHAWMICK, R
BISWAS, H
BANDYOPADHYAY, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 498 (01) : 81 - 83
[20] Electrochemistry of dimeric organopalladium(II) complexes containing bridging [pyridin-2-yl(phenyl)methyl-C,N](-) and [bis(pyridin-2-yl)phenylmethyl-C,N,N'](-) groups
Bond, AM
Canty, AJ
Cooper, JB
Tedesco, V
Traill, PR
Way, DM
[J]. INORGANICA CHIMICA ACTA, 1996, 251 (1-2) : 185 - 192

← 1 2 3 4 5 6 7 8 9 10 →