The effect of intercalation by 3d elements on the structure and physical properties of titanium diselenide MxTiSe2 (M = Cr, Fe, Co)

被引:46
作者
Kuranov, AV [1 ]
Pleshchev, VG [1 ]
Titov, AN [1 ]
Baranov, NV [1 ]
Krasavin, LS [1 ]
机构
[1] Ural State Univ, Yekaterinburg 620083, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/1.1324044
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The dependences of the structural parameters and the electrical and magnetic properties of titanium diselenide, intercalated by chromium, iron, and cobalt on the intercalant concentration and temperature were studied experimentally. The possibility of the involvement of d electrons in the formation of interlayer covalent bonds in relation to the 3d-shell filling of intercalated ion is discussed. (C) 2000 MAIK "Nauka/Interperiodica".
引用
收藏
页码:2089 / 2092
页数:4
相关论文
共 13 条
[1]  
Arnaud Y., 1976, J SOLID STATE CHEM, V17, P9
[2]  
Ashcroft N. W., 1973, SOLID STATE PHYS
[3]   THE IRON ELECTRONIC CHARACTERISTICS AND THE CRYSTAL DIMENSIONALITY OF THE PHASES FEX0.25TISE2, FE0.38TISE2, FE0.50TISE2 [J].
BUHANNIC, MA ;
COLOMBET, P ;
DANOT, M ;
CALVARIN, G .
JOURNAL OF SOLID STATE CHEMISTRY, 1987, 69 (02) :280-288
[4]  
FRIEND RH, 1982, REV CHIM MINER, V19, P467
[5]   ELECTRONIC-PROPERTIES OF INTERCALATION COMPLEXES OF THE TRANSITION-METAL DICHALCOGENIDES [J].
FRIEND, RH ;
YOFFE, AD .
ADVANCES IN PHYSICS, 1987, 36 (01) :1-94
[6]   LOCALIZED IMPURITY LEVEL AND CARRIER CONCENTRATION IN SELF-INTERCALATED TIS2 CRYSTALS [J].
INOUE, M ;
KOYANO, M ;
NEGISHI, H ;
UEDA, Y ;
SATO, H .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1985, 132 (01) :295-303
[7]   Effect of intercalation by silver on the charge-density-wave state in TiSe2 [J].
Krasavin, LS ;
Titov, AN ;
Antropov, VM .
PHYSICS OF THE SOLID STATE, 1998, 40 (12) :1962-1964
[8]  
KRUPICKA S, 1976, PHYSIK FERRITE VERWA, V1
[9]  
PANKRATOVA OY, 1993, ZH NEORG KHIM+, V38, P410
[10]   Electrical and magnetic properties of titanium diselenide intercalated with cobalt [J].
Pleshchev, VG ;
Titov, AN ;
Kuranov, AV .
PHYSICS OF THE SOLID STATE, 1997, 39 (09) :1442-1445