Scandium triflate-catalyzed Strecker-type reactions of aldehydes, amines and tributyltin cyanide in both organic and aqueous solutions. Achievement of complete recovery of the tin compounds toward environmentally-friendly chemical processes

被引：98

作者：

Kobayashi, S ^{[1
]}

Busujima, T

Nagayama, S

机构：

[1] Tokyo Univ Sci, Fac Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1620825, Japan

[2] Japan Sci & Technol Corp, CREST, Shinjuku Ku, Tokyo 1620825, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a801464g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Scandium triflate (CF3SO3-)-catalyzed Strecker-type reactions were successfully carried out by simply mixing aldehydes, amines and tributyltin cyanide at room temperature, to afford cr-amino nitriles in high yields. The reactions proceeded smoothly in both organic and aqueous solutions, and complete recovery of the tin materials has been achieved.

引用

页码：981 / 982

页数：2

共 20 条

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