New cluster condensation modes in early transition metal thiophosphates:: synthesis, structure and properties of CsTa4P3S19, a novel layered material

被引：21

作者：

Derstroff, V ^{[1
]}

Tremel, W ^{[1
]}

机构：

[1] Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a801155i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new layer compound CsTa4S5(S-2)(PS4)(3) was synthesized by the reaction of Ta metal in polythiophosphate melts. Its structure is based on Ta4S5(S-2) clusters which are condensed by PS43- groups.

引用

页码：913 / 914

页数：2

共 23 条

[1] REVIEW ON STRUCTURAL AND CHEMICAL-PROPERTIES OF TRANSITION-METAL PHOSPHORUS TRISULFIDES MPS3 [J].

BREC, R .

SOLID STATE IONICS, 1986, 22 (01) :3-30

[2] SYNTHESIS, CHARACTERIZATION, AND CRYSTAL-STRUCTURE OF A NEW TRULY ONE-DIMENSIONAL COMPOUND - PV2S10 [J].

BREC, R ;

OUVRARD, G ;

EVAIN, M ;

GRENOUILLEAU, P ;

ROUXEL, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1983, 47 (02) :174-184

[3]

BREC R, 1983, REV CHIM MINER, V20, P295

[4]

BREC R, 1995, PROGR INTERCALATION

[5]

COLOMBET P, 1987, J MAGN MAGN MATER, V11, P100

[6]

DERSTROFF V, UNPUB

[7]

DERSTROFF V, IN PRESS

[8] A new one-dimensional quaternary metal thiophosphate: Synthesis and structure of KNb2PS10 [J].

Do, J ;

Yun, H .

INORGANIC CHEMISTRY, 1996, 35 (13) :3729-&

[9] TA4P4S29 - A NEW TUNNEL STRUCTURE WITH INSERTED POLYMERIC SULFUR [J].

EVAIN, M ;

QUEIGNEC, M ;

BREC, R ;

ROUXEL, J .

JOURNAL OF SOLID STATE CHEMISTRY, 1985, 56 (02) :148-157

[10] UNUSUAL MOSSBAUER PHENOMENON IN LIXFEPS3 [J].

FATSEAS, GA ;

EVAIN, M ;

OUVRARD, G ;

BREC, R ;

WHANGBO, MH .

PHYSICAL REVIEW B, 1987, 35 (07) :3082-3087

← 1 2 3 →