1,4-phosphaboratabenzene:: A heteroaromatic π-ligand containing boron and phosphorus

被引：12

作者：

Ashe, AJ ^{[1
]}

Bajko, Z ^{[1
]}

Carr, MD ^{[1
]}

Kampf, JW ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 05期

关键词：

D O I：

10.1021/om0209733

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,4-dihydro-4-(diisopropylamino)-2,6-dimethyl-1-phenyl-1,4-phosphaborin (6) with Mn-2(CO)(10) affords 7, the Mn(CO)(3) complex of 4-(diisopropylamino)-2,6-dimethyl-1,4-phosphaboratabenzene. Reaction of 6 with Li followed by (Cp*RuCl](4) gives the ruthenium(II) complex 8. Crystal structures of 6-8 have been determined.

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页码：910 / 912

页数：3

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