Vacancies and voids in hydrogenated amorphous silicon

被引:245
作者
Smets, AHM [1 ]
Kessels, WMM [1 ]
van de Sanden, MCM [1 ]
机构
[1] Eindhoven Univ Technol, Ctr Plasma Phys & Radiat Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1063/1.1559657
中图分类号
O59 [应用物理学];
学科分类号
摘要
The hydride configurations in the hydrogenated amorphous silicon (a-Si:H) network have been studied by means of infrared absorption spectroscopy. The results on the film mass density of a-Si:H deposited by means of an expanding thermal plasma reveal the presence of two distinct regions in terms of hydrogen content and microstructure: below approximately 14 at. % H a-Si:H contains predominantly divacancies decorated by hydrogen, above 14 at. % H a-Si:H contains microscopic voids. These two distinct regions provide additional information on the origin of the low and high hydride stretching modes at 1980-2010 and 2070-2100 cm(-1), respectively. (C) 2003 American Institute of Physics.
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页码:1547 / 1549
页数:3
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