Chiral phosphine oxide BINAPO as a catalyst for enantioselective allylation of aldehydes with allyltrichlorosilanes

被引：86

作者：

Nakajima, M ^{[1
]}

Kotani, S

Ishizuka, T

Hashimoto, S

机构：

[1] Kumamoto Univ, Fac Med & Pharmaceut Sci, Kumamoto 8620973, Japan

[2] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 01期

关键词：

allylation; catalys; enantioselectivity; phosphine oxide;

D O I：

10.1016/j.tetlet.2004.10.168

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The effectiveness of chiral phosphine oxide BINAPO as a catalyst for the enantio elective addition of allyltrichlorosilanes to aldehydes was demonstrated, wherein the combination of diisopropylethylamine and tetrabutylammonium iodide as additives is crucial for accelerating the catalytic cycle. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：157 / 159

页数：3

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