Platinum catalyzed diboration using a commercially available catalyst:: Diboration of aldimines to α-aminoboronate esters

被引：91

作者：

Mann, G ^{[1
]}

John, KD ^{[1
]}

Baker, RT ^{[1
]}

机构：

[1] Univ Calif Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 14期

关键词：

D O I：

10.1021/ol006008v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Commercially available Pt(cod)Cl-2 catalyzes the diboration of alkenes, alkynes, and aldimines using bis(catecholato)diboron (cod = 1,5-cyclooctadiene). Catalyzed aldimine diboration provides the first direct route to alpha-aminoboronate esters. The diboration product from N-benzylidene-2,6-dimethylanilline is structurally characterized.

引用

页码：2105 / 2108

页数：4

共 26 条

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