Selective chemisorption of end-functionalized conjugated polymer on macro- and nanoscale-surfaces

被引：45

作者：

Nakashima, H ^{[1
]}

Furukawa, K ^{[1
]}

Ajito, K ^{[1
]}

Kashimura, Y ^{[1
]}

Torimitsu, K ^{[1
]}

机构：

[1] NTT Corp, Basic Res Labs, Mat Sci Res Lab, Atsugi, Kanagawa 2430198, Japan

来源：

LANGMUIR | 2005年 / 21卷 / 02期

关键词：

D O I：

10.1021/la048097g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Linear and conjugated poly(p-phenylene ethynylene)s (PPEs) with three different types of functionalized end groups (thiolacetate, isocyanide, and carboxylic acid groups) were synthesized, and their selective chemisorption behavior on various substrate surfaces were investigated using UV/vis transmission absorption spectroscopy. The UV/vis spectra of the PPEs were clearly dependent on the chemical affinity between the PPE end group and the solid surfaces. Furthermore, regarding the chemisorption of thiolacetate modified polymer on a nanoscopic gold particle surface. we visualized novel polymer-colloid nanoarchitectures such as a barbell-type nanohybrid and interconnected polymer nanowire structures that are successively linked through gold nanoparticles.

引用

页码：511 / 515

页数：5

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