Highly chemoselective oxidation of 1,5-diols to δ-lactones with TEMPO/BAIB

被引：159

作者：

Hansen, TM ^{[1
]}

Florence, GJ ^{[1
]}

Lugo-Mas, P ^{[1
]}

Chen, JH ^{[1
]}

Abrams, JN ^{[1
]}

Forsyth, CJ ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 01期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(02)02489-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The selective oxidative conversion of a variety of highly functionalized 1degrees,2degrees-1,5-diols into the corresponding delta-lactones has been effected simply and efficiently using a reagent system comprised of catalytic 2,2,6,6-tetramethylpiperidinooxy (TEMPO) and excess bis-acetoxyiodobenzene (BAIB). (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：57 / 59

页数：3

共 14 条

[11] A SELECTIVE AND EFFICIENT METHOD FOR ALCOHOL OXIDATIONS MEDIATED BY N-OXOAMMONIUM SALTS IN COMBINATION WITH SODIUM BROMITE [J].