RETRACTED: Highly monodisperse Pt(0)@AC NPs as highly efficient and reusable catalysts: the effect of the surfactant on their catalytic activities in room temperature dehydrocoupling of DMAB (Retracted article. See vol. 11, pg. 6889, 2021)

被引：51

作者：

Celik, Betul ^{[1
]}

Erken, Esma ^{[1
]}

Eris, Sinan ^{[1
]}

Yildiz, Yunus ^{[1
]}

Sahin, Birgutay ^{[1
]}

Pamuk, Handan ^{[1
]}

Sen, Fatih ^{[1
]}

机构：

[1] Dumlupinar Univ, Sen Res Grp, Dept Biochem, Fac Arts & Sci, Evliya Celebi Campus, TR-43100 Kutahya, Turkey

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 06期

关键词：

AMINE-BORANE ADDUCTS; METHANOL OXIDATION REACTION; METAL-ORGANIC FRAMEWORK; PLATINUM NANOPARTICLES; DIMETHYLAMINE-BORANE; TRANSITION-METAL; DEHYDROGENATION; CARBON; HYDROGEN; NANOCATALYST;

D O I：

10.1039/c5cy01371b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Addressed herein, we report the development of highly efficient and monodisperse Pt(0) nanoclusters for the dehydrocoupling of dimethylamine-borane (DMAB) which is considered to be one of the new hydrogen storage materials. The prepared Pt(0) nanoclusters were in situ generated for the first time from the reduction of PtCl4 and use of dipentylamine (DPA) and tripentylamine (TPA) ligands on activated carbon for the dehydrocoupling of dimethylamine-borane at room temperature and characterized by ICP-OES, XRD, TEM, HR-TEM, AFM, EDX, and XPS techniques. All the results show that highly crystalline and stable colloidal Pt(0)/DPA@AC and Pt(0)/TPA@AC nanoparticles have been formed and Pt(0)/DPA@AC and Pt(0)/TPA@AC were found to be two of the most active and long-lived catalysts with superior reusability performance in the dehydrocoupling of DMAB at room temperature.

引用

页码：1685 / 1692

页数：8

共 53 条

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