Air-Stable Secondary Phosphine Oxide or Chloride (Pre)Ligands for Cross-Couplings of Unactivated Alkyl Chlorides

被引：59

作者：

Ackermann, Lutz ^{[1
]}

Kapdi, Anant R. ^{[1
]}

Schulzke, Carola ^{[2
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 10期

关键词：

POSSESSING BETA-HYDROGENS; ARYL GRIGNARD-REAGENTS; DIRECT ARYLATIONS; C-C; HALIDES; CATALYSTS; PRELIGANDS; NICKEL; LIGANDS; ACID;

D O I：

10.1021/ol100658y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In situ generated and crystallographically well-defined, isolated palladium complexes derived from seven novel air-stable secondary phosphine oxides or chlorides enabled challenging Kumada-Corriu cross-couplings of unactivated alkyl chlorides bearing beta-hydrogens and proved applicable to transformations of alkyl-substituted organometallics.

引用

页码：2298 / 2301

页数：4

共 60 条

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