Vacuum-driven anionic ligand exchange in Buchmeiser-Hoveyda-Grubbs ruthenium(II) benzylidenes

被引:13
作者
Braddock, D. Christopher
Tanaka, Kiyotaka
Chadwick, David
Böhm, Volker P. W.
Roeper, Michael
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, London SW7 2AZ, England
[3] BASF AG, Ludwigshafen, Germany
关键词
ruthenium benzylidene; metathesis; solid-supported catalyst;
D O I
10.1016/j.tetlet.2007.05.108
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Vacuum-driven anionic ligand exchange of a perfluorocarboxylic acid with ruthenate-bound perfluorocarboxylates is demonstrated and allows for a novel entry to solid-supported ruthenium benzylidenes. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5301 / 5303
页数:3
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