Rutheninm-catalyzed yne-ene cross metathesis immobilization of functionalized alkynes

被引：43

作者：

Schuster, M ^{[1
]}

Blechert, S ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Organ Chem, D-10623 Berlin, Germany

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 16期

关键词：

D O I：

10.1016/S0040-4039(98)00245-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium initiator 1 efficiently catalyzes the crossed metathesis' between functionalized terminal alkynes and allylsilyl polystyrene 2. This selective yne-ene metathesis yields polymer-supported 1,3-dienes and represents a novel catalytic immobilization method. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2295 / 2298

页数：4

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