A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

被引：37

作者：

Tandon, Santokh S.

Bunge, Scott D.

Thompson, Laurence K.

机构：

[1] Kent State Univ, Dept Chem, Salem, OH 44460 USA

[2] Kent State Univ, Dept Chem, Kent, OH 44242 USA

[3] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 08期

关键词：

D O I：

10.1039/b612795a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,6-Diformyl-4-methylphenol and 1,3-diamino-2-hydroxypropane template condense in the presence of Cu(NO3)(2) and azide to produce a 3 : 3 macrocyclic ring containing an unprecedented grouping of seven copper(II) ions within the macrocyclic cavity, with the seventh metal completing a body-centred heptanuclear lattice.

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页码：798 / 800

页数：3

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