Response to steric constraint by d10 cations:: an 'A-frame' disilver cryptate

被引:13
作者
Coyle, JL
McKee, V
Nelson, J [1 ]
机构
[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
[2] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England
关键词
D O I
10.1039/a708408k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A pair of silver(I) cations is accommodated within a small azacryptand which adopts an A-frame conformation, allowing both intra-and inter-cryptate bonding of silver cations.
引用
收藏
页码:709 / 710
页数:2
相关论文
共 19 条
[1]  
ALOBAIDI A, UNPUB INORG CHEM
[2]  
APPERLY D, UNPUB
[3]   PT(O)-PT(O) DIMERS - BONDING RELATIONSHIPS IN A D10-D10 SYSTEM [J].
DEDIEU, A ;
HOFFMANN, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (07) :2074-2079
[4]   A NEW DITOPIC POLYAZA MACROBICYCLIC LIGAND - X-RAY CRYSTALLOGRAPHIC STRUCTURE DETERMINATION [J].
DREW, MGB ;
MCDOWELL, D ;
NELSON, J .
POLYHEDRON, 1988, 7 (21) :2229-2232
[5]   CASCADE COMPLEXES OF AN OCTAAZA CRYPTAND - COORDINATED AZIDE WITH LINEAR M-NNN-M GEOMETRY [J].
DREW, MGB ;
HUNTER, J ;
MARRS, DJ ;
NELSON, J ;
HARDING, C .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (22) :3235-3242
[6]   Thiophene-linked azacryptand sites for dicopper and disilver; Thiophene sulfur as an inert spacer? [J].
Drew, MGB ;
Harding, CJ ;
Howarth, OW ;
Lu, Q ;
Marrs, DJ ;
Morgan, FF ;
McKee, V ;
Nelson, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (14) :3021-3030
[7]  
DREW MGB, UNPUB J CHEM SOC DA
[8]   SPECTROSCOPIC STUDIES ON THE AVERAGE-VALENCE COPPER SITE [CU-2](3+) [J].
FARRAR, JA ;
MCKEE, V ;
ALOBAIDI, AHR ;
MCGARVEY, JJ ;
NELSON, J ;
THOMSON, AJ .
INORGANIC CHEMISTRY, 1995, 34 (06) :1302-&
[9]   The electronic structure of mixed-valence copper dimer [Cu-2{N(CH2CH2N=CHCH=NCH2CH2)(3)N}](3+) [J].
Farrar, JA ;
Grinter, R ;
Neese, F ;
Nelson, J ;
Thomson, AJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (21) :4083-4087
[10]   A COPPER-COPPER BOND BY INTENT [J].
HARDING, C ;
NELSON, J ;
SYMONS, MCR ;
WYATT, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (21) :2499-2500