Group 10 phosphinite POCOP pincer complexes derived from 4-n-dodecylresorcinol: An alternative way to produce non-symmetric pincer compounds

被引：58

作者：

Agustin Solano-Prado, Moises ^{[1
]}

Estudiante-Negrete, Fabiola ^{[1
]}

Morales-Morales, David ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

POLYHEDRON | 2010年 / 29卷 / 01期

关键词：

PCP pincer compounds; POCOP pincer compounds; Cross coupling reactions; Heck reaction; Suzuki-Miyaura reaction; Catalysis; X-RAY-STRUCTURE; PALLADIUM COMPLEXES; CATALYTIC-PROPERTIES; PCP; NCN; COORDINATION; EFFICIENT; ORGANOMETALLICS; DEHYDROGENATION; SUBSTITUTION;

D O I：

10.1016/j.poly.2009.07.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Phosphinite POCOP pincer compounds 14-(n-C12H25)-C-6-H-3-1,3-(OPR2)(2)] R=Ph (1), Pr-i (2) derived from 4-n-dodecylresorcinol and their group 10 derivatives [MCI{3-(n-C12H25)-C6H2-2,6-(OPR2)(2)}] M(R) = Ni(Ph) (3), Ni(Pr-i) (6), Pd(Ph) (4), Pd(Pr-i) (7) and Pt(Ph) (5), Pt(Pr-i) (8) were synthesized and the catalytic activity of the palladium species explored in the Mizoroki-Heck and Suzuki-Miyaura cross coupling reactions. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：592 / 600

页数：9

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