Magnetic-Field-Assisted Layer-by-Layer Electrostatic Assembly of Ferromagnetic Nanoparticles

被引:33
作者
Dey, Sukumar [1 ]
Mohanta, Kallol [1 ]
Pal, Amlan J. [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
关键词
CDSE NANOPARTICLES; ELECTRICAL BISTABILITY; FILMS; POLYELECTROLYTES; MULTILAYERS; ADSORPTION; DIODES;
D O I
10.1021/la101132z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report that layer-by-layer (LbL) electrostatic assembly of Fe3O4 nanoparticles can be supplemented by orienting magnetic domains of the nanoparticles. With the oriented domains of ionic-capped nanoparticles, both magnetic and electrostatic forces of attraction become operative during the LbL deposition process. The magnetic-field-assisted LbL adsorption process has been evidenced by increased electronic absorbance of the films. While atomic force microscopy studies rule out formation of multiple layers during a single adsorption process, magnetic force microscopy images evidence oriented domains in the LbL films. The results show a novel route for LbL deposition of ferromagnetic nanoparticles with oriented magnetic domains in the thin films.
引用
收藏
页码:9627 / 9631
页数:5
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