Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides

被引：45

作者：

Bejan, Iulia

Gueclue, Denis

Inoue, Shigeyoshi

Ichinohe, Masaaki

Sekiguchi, Akira

Scheschkewitz, David

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 18期

关键词：

Group; 14; elements; low-valent compounds; silenes; silicon; small-ring systems;

D O I：

10.1002/anie.200700067

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyramidal silicon centers within the Si=C bond are the most prominent feature of the first cyclic silenes stable at room temperature, as exhibited by X-ray diffraction (see structure) and calculations. They are quantitatively formed by reaction of lithium disilenides, disila analogues of vinyllithium compounds, with acid chlorides, and are relatively inert, for example, towards the addition of MeOH. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH S. Co. KGaA.

引用

收藏

页码：3349 / 3352

页数：4

相关论文

共 47 条

[11] Evidence for formation of silenes strongly influenced by reversed Si=C bond polarity [J].

El-Sayed, I ;

Guliashvili, T ;

Hazell, R ;

Gogoll, A ;

Ottosson, H .

ORGANIC LETTERS, 2002, 4 (11) :1915-1918

[12] Silenes ⟩Si=C⟨, germenes ⟩Ge-C⟨ and stannenes ⟩Sn=C⟨ -: The French contribution [J].

Escudié, J ;

Couret, C ;

Ranaivonjatovo, H .

COORDINATION CHEMISTRY REVIEWS, 1998, 178 :565-592

[13] 2,3-DISILAOXETANES FROM TETRAMESITYLDISILENE - SYNTHESIS AND PHOTOLYSIS [J].

FANTA, AD ;

DEYOUNG, DJ ;

BELZNER, J ;

WEST, R .

ORGANOMETALLICS, 1991, 10 (10) :3466-3470

[14] REACTIONS OF TETRAMESITYLDISILENE WITH ACID-CHLORIDES AND KETENES [J].

FANTA, AD ;

BELZNER, J ;

POWELL, DR ;

WEST, R .

ORGANOMETALLICS, 1993, 12 (06) :2177-2181

[15]

FRISCH MJ, GAUSSIAN 98 REVISION

[16] The first isolable 2-silenolate [J].

Guliashvili, T ;

El-Sayed, I ;

Fischer, A ;

Ottosson, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (14) :1640-1642

[17]

Guliashvili T., 2003, ANGEW CHEM, V115, P1678

[18] Hetero-π-systems from 2+2 cycloreversions.: Part 1.: Gusel'nikov -: Flowers route to silenes and origination of the chemistry of doubly bonded silicon [J].

Gusel'nikov, LE .

COORDINATION CHEMISTRY REVIEWS, 2003, 244 (1-2) :149-240

[19] THERMAL DECOMPOSITION OF 1,1-DIMETHYL-1-SILACYCLOBUTANE AND SOME REACTIONS OF AN UNSTABLE INTERMEDIATE CONTAINING A SILICON-CARBON DOUBLE BOND [J].

GUSELNIKOV, LE ;

FLOWERS, MC .

CHEMICAL COMMUNICATIONS, 1967, (17) :864-+

[20] Disilenyllithium from tetrasila-1,3-butadiene: A silicon analogue of a vinyllithium [J].

Ichinohe, M ;

Sanuki, K ;

Inoue, S ;

Sekiguchi, A .

ORGANOMETALLICS, 2004, 23 (13) :3088-3090

← 1 2 3 4 5 →