Enantioselective sensing of chiral carboxylic acids

被引：165

作者：

Mei, XF ^{[1
]}

Wolf, C ^{[1
]}

机构：

[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 45期

关键词：

D O I：

10.1021/ja0459781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral 1,8-diacridylnaphthalene-derived fluorosensor has been prepared and used for enantioselective sensing of a broad variety of chiral carboxylic acids including amino acids, aliphatic acids, arylalkanoic acids, and halogenated carboxylic acids. Fluorescence titration experiments in acetonitrile gave linear Stern-Volmer plots for 1:1 and 1:2 complexes and enantioselectivities up to 4.5. Copyright © 2004 American Chemical Society.

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页码：14736 / 14737

页数：2

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