Self-assembly of a novel 3D open framework from Anderson-type polyoxoamons

被引：26

作者：

An, HY ^{[1
]}

Wang, EB ^{[1
]}

Xiao, DR ^{[1
]}

Li, YG ^{[1
]}

Xu, L ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 03期

基金：

中国国家自然科学基金;

关键词：

self-assembly; open frameworks; Anderson-type polyoxoanions;

D O I：

10.1016/j.inoche.2004.12.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polyoxoanion-based compound, Na-4[Pr(H2O)(5)](2)[IMo6O24](2) . 7H(2)O (1), has been synthesized and characterized by elemental analyses, IR, XPS, TG, and single crystal X-ray diffraction. Compound 1 possesses a unique three-dimensional open framework composed Of [IMo6O24](5-) polyoxoanions covalently linked by praseodymium cations, containing "guest" sodium ions and water molecules in the rectangular channels. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：267 / 270

页数：4

共 52 条

[1] A novel chain-like polymer constructed from heteropolyanions covalently linked by lanthanide cations:: (C5H9NO2)2[La(H2O)7CrMo6H6O24]•11H2O (proline=C5H9NO2) [J].

An, HY ;

Lan, Y ;

Li, YG ;

Wang, E ;

Hao, N ;

Xiao, DR ;

Duan, LY ;

Xu, L .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (03) :356-358

[2] A novel organic-inorganic hybrid with Anderson type polyanions as building blocks:: [(Gly)2Cu][Na(H2O)4Cr(OH)6Mo6O18]•9.5H2O (Gly = glycine) [J].

An, HY ;

Guo, YQ ;

Li, YG ;

Wang, EB ;

Lü, J ;

Xu, L ;

Hu, CW .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (04) :521-523

[3] Constitution of the poly-acids [J].

Anderson, JS .

NATURE, 1937, 140 :850-850

[4] Multi-iron silicotungstates: Synthesis, characterization, and stability studies of polyoxometalate dimers [J].

Anderson, TM ;

Neiwert, WA ;

Hardcastle, KI ;

Hill, CL .

INORGANIC CHEMISTRY, 2004, 43 (23) :7353-7358

[5]

Biradha K, 2000, ANGEW CHEM INT EDIT, V39, P3843, DOI 10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO

[6]

2-#

[7] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[8] Hybrid molecular materials based upon magnetic polyoxometalates and organic π-electron donors:: Syntheses, structures, and properties of bis(ethylenedithio)tetrathiafulvalene radical salts with monosubstituted Keggin polyoxoanions [J].

Coronado, E ;

Galán-Mascarós, JR ;

Giménez-Saiz, C ;

Gómez-García, CJ ;

Triki, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (19) :4671-4681

[9]

Cronin L, 2002, ANGEW CHEM INT EDIT, V41, P2805, DOI 10.1002/1521-3773(20020802)41:15<2805::AID-ANIE2805>3.0.CO

[10]

2-E

← 1 2 3 4 5 6 →