Straightforward detection of the secondary ionisation of the phosphate group and pK determinations by high-resolution solid-state 31P NMR

被引:13
作者
Gardiennet, C
Henry, B
Kuad, P
Spiess, B
Tekely, P [1 ]
机构
[1] Univ Nancy 1, CNRS, UMR 7565, F-54506 Vandoeuvre Les Nancy, France
[2] Univ Strasbourg 1, Fac Pharm, CNRS, UMR 7081, F-67401 Illkirch Graffenstaden, France
关键词
D O I
10.1039/b413415j
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
The suitability of high-resolution solid-state P-31 NMR for a straightforward determination of the protonation state of phosphate groups as well as of their pK(2) values extracted from solid state mono : dianionic ratios has been demonstrated.
引用
收藏
页码:180 / 182
页数:3
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