Oxygen reduction on anodically formed titanium dioxide

被引:88
作者
Mentus, SV [1 ]
机构
[1] Univ Belgrade, Fac Phys Chem, YU-11000 Belgrade, Serbia And Mont, Serbia
关键词
oxygen reduction reaction; reaction path; rotating disk electrode; titanium dioxide; voltammetry;
D O I
10.1016/j.electacta.2004.07.009
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Oxygen reduction on anodically formed TiO2 was studied in both alkaline and acidic water solutions, using dc voltammetry combined with the rotating disk technique. The possible interference with hydrogen evolution reaction was considered. By means of Levich-Koutecky plot, in alkaline media, 4e(-) reduction path was confirmed, while with the transition to acidic media, the rising participation of the indirect, 2e(-) reduction path was evidenced. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:27 / 32
页数:6
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